:term:`S ` """"""""""""""""""""" The value of the spin quantum number :math:`S` is given by this option. The default is determined by the value of the multiplicity. This is used for two things: (1) determining the phase of the redundant half of the CI vector when the :math:`M_s = 0` component is used (i.e., :term:`MS0 ` = ``TRUE``), and (2) making sure the guess vector has the desired value of :math:`\langle S^2\rangle` (if :term:`S_SQUARED ` is ``TRUE`` and :term:`ICORE ` = ``1``). * **Type**: double * **Default**: 0.0