:term:`OPT_METHOD ` """"""""""""""""""""""""""""""""""""" The optimization algorithm. Modified Steepest-Descent (MSD) takes a Newton-Raphson (NR) step with a crude approximation to diagonal elements of the MO Hessian. The ORB_RESP option obtains the orbital rotation parameters by solving the orbital-reponse (coupled-perturbed CC) equations. Additionally, for both methods a DIIS extrapolation will be performed with the DO_DIIS = TRUE option. * **Type**: string * **Possible Values**: MSD, ORB\_RESP * **Default**: ORB\_RESP